🧪 Fixed-Bed Adsorption Breakthrough (Thomas & BDST)

Model dynamic packed-bed adsorption breakthrough curves (S-curves), exhaustion times, Bed Depth Service Time (BDST), and Mass Transfer Zone (MTZ) migration.

⚡ Fortran 90 Engine Double Precision (IEEE 754) ✓ ISO / ASME Validated
📊 Solver Telemetry ● ACTIVE
👁️ Consultations 33
⚡ Calculs faits 29
💾 Téléchargements 263 📦 Code Fortran 6.4 KB
📅 Mise en service Jun 2026
⏱️ Latence < 1 ms
⚡ Outils & Rapports :
💾 Télécharger Fortran 90

🧪 Packed Adsorbent Bed Mass Transfer Wave Front Migration

Real-time visual simulation of solute adsorption gradient wave advancing through porous bed

📝 Configuration & Presets

🪨 GAC Phenol (350 L/h) 🪵 Biochar Heavy Metal (Pb²⁺) 💎 Zeolite PFAS Trace Bed 🎨 Textile Dye Decolorization
📐 Column Dimensions & Adsorbent
GAC: ~450–550 g/L, Zeolite: ~700–850 g/L
💧 Fluid Flow & Thomas Kinetics
Typical range: 0.05 to 0.50 mL/(mg·min)
Thomas & BDST Formulations:
• Thomas S-Curve: C/C₀ = 1 / [ 1 + exp( (kTh q₀ M / Q) − kTh C₀ t ) ]
• Breakthrough Time (5%): tb = t₅₀ − ln(19) / (kTh C₀)
• Exhaustion Time (95%): ts = t₅₀ + ln(19) / (kTh C₀)
• Critical Bed Depth: Z₀ = (u₀ / (kBA N₀)) · ln(C₀/Cb − 1)

📊 Breakthrough Performance Results

Configure inputs and click Compute to view results.

📘 Calculation Methodology & Adsorption Kinetics Standards

Thomas Column Model

The Thomas model assumes plug flow with second-order reversible Langmuir adsorption kinetics, providing the classic analytical S-curve:

C/C₀ = 1 / [ 1 + exp( (kTh q₀ M / Q) − kTh C₀ t ) ]

Bed Depth Service Time (BDST)

BDST relates service time linearly to bed depth. The x-intercept represents the critical depth $Z_0$ below which instantaneous breakthrough occurs.

Key Engineering Assumptions

  • Isothermal operation with negligible axial fluid dispersion.
  • Breakthrough criterion defined at $C/C_0 = 5\%$ ($0.05$).
  • Exhaustion criterion defined at $C/C_0 = 95\%$ ($0.95$).